长江经济带工业集聚对水环境污染的影响——基于空间计量与门槛效应的检验

经济发展与生态环境动态良性循环已经成为社会经济发展的重要议题。为实现长江经济带高质量发展，以2007—2018年长江经济带11个省市为样本，采用空间计量和面板门槛模型考察工业集聚与水环境污染之间的关系。研究表明：长江经济带各省市水环境污染具有显著的空间自相关性；长江经济带工业集聚水平和水环境污染表现出先降低后增强的“U”形变化特征，说明工业集聚水平对水环境污染的影响存在一个阈值；长江经济带工业集聚产生的规模效应和结构效应对水环境污染存在显著的双门槛效应，在不同的工业集聚水平下，规模效应和结构效应表现出不同的外部性特征；工业集聚产生的技术溢出效应对水环境污染的影响同样具有显著的双门槛作用；随着各地区工业集聚水平的提高，技术溢出效应对水环境污染的减排作用表现出先强后弱的趋势。     

庄旺煤矿综放工作面顶煤冒放性分析

结合庄旺煤矿50208综放工作面煤层赋存特征,系统分析了开采深度、煤层强度、煤层厚度、煤层夹矸、煤层顶板及顶煤节理裂隙对综放工作面顶煤冒放性的影响,并通过隶属度法对庄旺煤矿顶煤冒放性的影响因素进行计算,做出综合评价,最终计算得工作面顶煤冒放性隶属度值μ为0.701,冒放等级为中等。因此,庄旺煤矿采用综采放顶煤回采工艺是可行的。     

Reactivity of flavanols: Their fate in physical food processing and recent advances in their analysis by depolymerization

Flavanols, a subgroup of polyphenols, are secondary metabolites with antioxidant properties naturally produced in various plants (e.g., green tea, cocoa, grapes, and apples); they are a major polyphenol class in human foods and beverages, and have recognized effect on maintaining human health. Therefore, it is necessary to evaluate their changes (i.e., oxidation, polymerization, degradation, and epimerization) during various physical processing (i.e., heating, drying, mechanical shearing, high-pressure, ultrasound, and radiation) to improve the nutritional value of food products. However, the roles of flavanols, in particular for their polymerized forms, are often underestimated, for a large part because of analytical challenges: they are difficult to extract quantitatively, and their quantification demands chemical reactions. This review examines the existing data on the effects of different physical processing techniques on the content of flavanols and highlights the changes in epimerization and degree of polymerization, as well as some of the latest acidolysis methods for proanthocyanidin characterization and quantification. More and more evidence show that physical processing can affect content but also modify the structure of flavanols by promoting a series of internal reactions. The most important reactivity of flavanols in processing includes oxidative coupling and rearrangements, chain cleavage, structural rearrangements (e.g., polymerization, degradation, and epimerization), and addition to other macromolecules, that is, proteins and polysaccharides. Some acidolysis methods for the analysis of polymeric proanthocyanidins have been updated, which has contributed to complete analysis of proanthocyanidin structures in particular regarding their proportion of A-type proanthocyanidins and their degree of polymerization in various plants. However, future research is also needed to better extract and characterize high-polymer proanthocyanidins, whether in their native or modified forms.     

加工精度对方便米饭理化性质的影响

过度"精、细、白"的大米加工方式造成大量的粮食和营养浪费。为促进我国粮食适度加工政策的实施,研究大米加工精度(DOM)对方便米饭复水性质(水分含量和水分分布)、形态特征(长宽比、延长率和体积膨胀率)、颜色(L值、b值和ΔE值)、质构(硬度和黏度)和微观结构的影响及规律。结果表明,当DOM≥3%时,方便米饭的水分吸收速率、水分分布和形态特征与精白米方便米饭(DOM 12%)相近。当DOM升至6%时,方便米饭的形态特征、总体颜色ΔE值、硬度和微观结构也与精白米方便米饭相近。当DOM达到9%时,方便米饭的黏度已与精白米方便米饭无显著差异。由此可见,生产方便米饭的大米DOM范围宜为6%～9%。用此DOM范围的大米生产方便米饭,可以保留部分糠层营养物质,节约3%～6%的粮食。     

Design and synthesis of side-chain optimized poly(2,6-dimethyl-1,4-phenylene oxide)-g-poly(styrene sulfonic acid) as proton exchange membrane for fuel cell applications: Balancing the water-resistance and the sulfonation degree

Side-chain optimized poly (2,6-dimethyl-1,4-phenylene oxide)-g-poly (styrene sulfonic acid) (PPO-g-PSSA) is designed with balanced water-resistance and sulfonation degree. The PPO-g-PSSA is synthesized by controlled atom-transfer radical polymerization (ATRP) from brominated poly (2,6-dimethyl-1,4-phenylene oxide) (PPO-xBr) and ethyl styrene-4-sulfonate and followed by hydrolysis. A series of PPO-g-PSSA are prepared possessing different bromination degree (x) of PPO-xBr and polymerization degree (m) of the side-chains and the water-resistances of the fabricated membranes are investigated. The results show that a PPO-g-PSSA at relatively low x (x < 0.2) and high m (m > 4) exhibits good balance between the water-resistance and the sulfonation degree. Namely, it displays suitable proton conductivity with compromised water-resistance. Moreover, a maximum ion exchange capacity (IEC) of 3.24 mmol g^?1 is reached without the sacrifice of water-resistance. In addition, PPO-g-0.08PSSA-13 and PPO-g-0.14PSSA-4 are chosen characterized by thermogravimetric analysis, proton conductivities and mechanical properties. At 90% RH, the optimized PPO-g-0.08PPSA-13 possesses a proton conductivity of 37.9 mS cm^?1 at 40 °C and 45.5 mS cm^?1 at 95 °C, respectively.     

我国环境土壤中的重要超铀核素分布

Pu、Am、Np是3种重要的超铀核素，环境中的这些核素主要来源于人类的核活动，包括大气层核武器试验、核设施排放和核事故释放等。这些超铀核素不仅具有放射性，还兼具化学毒性。我国地域辽阔，环境土壤类型丰富，在当前核电事业蓬勃发展的背景下，建立和扩大我国环境土壤中这些重要超铀核素的“准本底”数据库是辐射环境安全评价的重要组成部分，也是公众关心的热点问题。近30多年来，研究人员对我国不同环境土壤中这几种超铀核素从不同科学角度开展了调查测量研究。本文对此进行整理和分析，对我国环境土壤中这些重要超铀核素（主要是Pu核素，还包括241Am和237Np）的来源、浓度水平和分布特征进行讨论和综述，为辐射环境安全评价奠定基础。     

Study of spatial and temporal evolution of Ar and F atoms in SF6/Ar microsecond pulsed discharge by optical emission spectroscopy

The study of sulfur hexafluoride (SF₆) discharge is vital for its application in gas-insulated equipment. Direct current partial discharge (PD) may cause SF₆ decomposition, and the decomposed products of SF₆, such as F atoms, play a dominant role in the breakdown of insulation systems. In this study, the PD caused by metal protrusion defects is simulated by a needle-plate electrode using pulsed high voltage in SF₆/Ar mixtures. The spatial and temporal characteristics of SF6/Ar plasma are analyzed by measuring the emission spectra of F and Ar atoms, which are important for understanding the characteristics of PD. The spatial resolved results show that both F and Ar atom spectral intensities increase first from the plate anode to the needle and then decrease under the conditions of a background pressure of 400 Pa, peak voltage of −1000 V, frequency of 2 kHz, pulse width of 60 μs, and electrode gap of 5–9 mm. However, the distribution characteristics of F and Ar are significantly different. The temporal distribution results show that the spectral intensity of Ar decreases first and then increases slowly, while the spectral intensity of F increases slowly for the duration of the pulsed discharge at the electrode gap of 5 mm and the pulse width of 40–80 μs.     

镁质熔剂性球团矿相的多重分形谱

 球团矿相微观结构决定其冶金物理化学性能，为透视球团矿微观结构与其宏观冶金物理化学性能之间的依赖关系，需要解决的首要关键问题是矿相微观视觉特征的提取与定量表征。以镁质熔剂性球团微观矿相为研究对象，在直观分析矿相视觉特征的基础上，采用多重分形谱分析方法，提取矿相的微观多重分形谱定量表征值f（α），并分别深度挖掘由f（α）衍生出的对称度特征值Δf、谱宽特征值Δα、容量维特征值D（0）随碱度变化的迁移规律和随矿相检测位置变化的迁移规律。研究结果表明，矿相微观视觉特征在HSV颜色空间上呈现的颜色特征未在碱度变化和位置变化上存在显著差异性；矿相微观多重分形谱分析中，Δf、Δα、D（0） 3个特征值在碱度变化和位置变化上有显著的差异性，可以很好地表征碱度迁移规律和位置迁移规律。